• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    The present invention relates to an exhaust system (1) for purifying exhaust gases of an internal combustion engine (2), in particular a diesel engine of a motor vehicle, in which exhaust gases flow in a specific flow direction (3). This exhaust system 1 is particularly contained in a catalytic converter 4 for converting carbon monoxide and hydrocarbons contained in the exhaust gas, in particular an oxidation catalytic converter 5 for converting nitrogen monoxide contained in the exhaust gas, and in the exhaust gas. And a particle trap 6 for trapping the collected particles, all of which are arranged in series in the flow direction 3. The gas exhaust system 1 ensures a fairly efficient conversion of the harmful substances contained in the exhaust gas, in particular producing a particularly pronounced effect on the regeneration of the particle trap 6.
    公开号:KR20040010621A
    申请号:KR10-2003-7013338
    申请日:2001-10-11
    公开日:2004-01-31
    发明作者:롤프 브뤽
    申请人:에미텍 게젤샤프트 퓌어 에미시온스테크놀로기 엠베하；
    IPC主号:
    专利说明:

    Exhaust System {EXHAUST GAS SYSTEM}
    [2] Due to statutory provisions requiring higher than previous conditions for exhaust systems used in automotive engineering, these exhaust systems have been a continuing theme from the past to the present. This entails the use of a wide range of components which each perform different functions within the exhaust system. For example, starting catalytic converters are known, and these converters have a particularly small volume so that the cold start of the internal combustion engine is followed by a rapid starting temperature for the catalytic conversion. Also, by way of example, electrically heated catalytic converters are known, in which the exhaust system likewise improves cold starting performance. What is known as an absorber in the exhaust system of an internal combustion engine serves to absorb any contaminants present in the exhaust gas for a period of time, which are preferably stored downstream until the catalytic converter reaches its operating temperature. . Particulate traps or particle filters are also used, particularly in diesel engine exhaust systems, which collect carbon-based particles contained in exhaust gases, which collect, for example, high levels of thermal energy. By supplying it is converted continuously or discontinuously.
    [1] The present invention relates to an exhaust system for purifying exhaust gases from an internal combustion engine, in particular for purifying exhaust gases coming from a diesel engine of a motor vehicle.
    [22] 1 shows an embodiment of an exhaust system.
    [23] 2 is a plan view of a component of an exhaust system having a honeycomb;
    [24] 3 is an illustrative detailed view of an embodiment of a particle trap of an exhaust system.
    [25] 4 shows another embodiment of an exhaust system arranged in proximity to the engine.
    [26] Explanation of symbols on the main parts of the drawings
    [27] 1: exhaust system 2: internal combustion engine
    [28] 3: flow direction 4: catalytic converter
    [29] 5: oxidation catalytic converter 6: particle trap
    [30] 7: turbocharger 8: exhaust manifold
    [31] 9: John 10: Street
    [32] 11: total volume 12: volume
    [33] 13: passage 14: turbulence point
    [34] 15: silent point 16: diverter device
    [35] 17: converter volume 18: catalytic converter volume
    [36] 19: honeycomb 20: structured metal foil
    [37] 21 cylinder 22 tubular casing
    [38] 23: flat metal foil 24: hole
    [39] 25: opening 26: housing
    [40] 27: fresh air supply unit 28: exhaust manifold
    [41] 29: distance
    [3] It is an object of the present invention to effectively convert contaminants present in exhaust gases, in order to purify the exhaust gases from the internal combustion engine, in particular from the diesel engines of automobiles, and to continuously filter the particulate traps arranged in the exhaust system. It is to provide an exhaust system that ensures regeneration.
    [4] The object of the invention is achieved by an exhaust system having the features of claim 1. Further preferred configurations of the exhaust gases are described in the dependent claims.
    [5] Exhaust gases from an internal combustion engine, in particular from a diesel engine of a motor vehicle, can be flowed through the exhaust system according to the invention for purification in the desired flow direction, which comprises the following continuous parts when viewed in the flow direction. .
    [6] 1. Catalytic converters for converting carbon monoxide and hydrocarbons, especially those contained in exhaust gases,
    [7] 2. oxidation catalytic converter for converting nitrogen monoxide, especially contained in exhaust gas, and
    [8] 3. Particle traps for collecting particles contained in exhaust gas.
    [9] The proposed configuration of the above mentioned components in the exhaust system has a particularly beneficial effect on the regeneration of the particle trap. These good effects are unexpected results from the above-mentioned parts connected in series, as described in more detail below.
    [10] Upstream catalytic converters are particularly used for converting carbon monoxide and hydrocarbons. The total carbon monoxide content contained in the exhaust gas from the diesel engine is relatively low and only increases significantly when certain limits are reached. This is caused by the general lean operating strategy (in excess of air) of the diesel engine, in particular in terms of fuel consumption. In this case, high levels of hydrocarbons are generated, for example, in the excess lean fuel / air mixing zone, and they cannot be converted in time at low temperatures in the combustion chamber (partial load mode). An increase in the hydrocarbon content in the exhaust gas is also present in the case of temporarily very rich combustion (air lean). In particular, when the catalytic converter is arranged close to the engine, the catalytic converter converts very specific contaminants (especially carbon monoxide and unsaturated hydrocarbons) contained in the exhaust gas well, and these processes are quick and easy considering the high temperature in the vicinity of the engine. In fact, it happens completely.
    [11] Due to the fact that the catalytic converter has already converted most of the carbon monoxide and unsaturated hydrocarbons, the downstream catalytic converter is used to convert nitrogen oxides, especially those still present in the exhaust gas. High levels of nitrogen oxides are produced, especially in the case of substantial stoichiometric combustion, up to the appropriate excess air of the air (up to about λ = 3). In this case, the nitrogen dioxide content in the exhaust gas is generally between 5 and 15%. Existing oxidation catalytic converters have a catalytically active coating, which converts nitrogen monoxide to nitrogen dioxide. This results in a significant increase in the nitrogen dioxide content in the exhaust gas, suitably at a level of at least 50%, in particular at least 80% or even up to 95%. The rate of conversion of this property is achieved because the catalytic converter disposed upstream has already converted most of the additional contaminants into harmless components. The high nitrogen dioxide content produced by the oxidation catalytic converter in this way has a particularly beneficial effect on the regeneration of the downstream particle traps.
    [12] Particles, especially carbon-based particles, are present in the exhaust gas when the fuel is burned to an extreme deficiency, and represent combustion in diesel engines due to locally significant inhomogeneous fuel-air mixing. These particles usually tend to deposit on the outer wall of the exhaust system, for example in the exhaust section and / or on the coating of the part. Then, in the case of load change, these stacked particles are released in the form of a cloud of particles. These particles are retained and continuously converted chemically as a result of diffusion and absorption phenomena by particle traps arranged downstream in accordance with the present invention. This ensures continuous regeneration of the particle trap and prevents the flow path inside the particle trap from becoming blocked. This regeneration process is greatly facilitated by nitrogen dioxide, which was previously regenerated by an oxidation catalytic converter. As a result, on the one hand, effective conversion of the carbon-based particles is ensured, and on the other hand, the flow path is blocked to prevent the pressure in the exhaust system from rising. In this specification, all parts are preferably arranged in close proximity to the engine, in particular the engine, not the undercarriage of the motor vehicle. This ensures a sufficiently high temperature over the operating life of the internal combustion engine (even immediately after the Colt start), so that the current emissions guidelines may be required with significant differences regarding the individual pollutants remaining in the exhaust gases. have.
    [13] According to another configuration of the exhaust system, this configuration includes a turbocharger, a catalytic converter arranged upstream of the turbocharger, and an oxidation catalytic converter arranged downstream of the turbocharger, in the flow direction. Turbocharging is a method of improving the power of an internal combustion engine, and is particularly used in connection with diesel engines. During turbocharging, the actuating machine compresses the air needed for the engine combustion process, allowing a larger mass of air to pass through the internal combustion engine into the combustion chamber or cylinder every cycle. For this purpose, the compressor is driven by, for example, a turbocharge using energy of exhaust gas. Coupling to the engine is purely thermal in this case, not mechanical, and the principle of ram charging used in the automotive industry is important. By arranging the catalytic converter upstream of the turbocharger of this nature, it is possible to prevent the loss of heat from the exhaust gas as a result of contact with the components of the turbocharger in this way, thus ensuring that the operating temperature of the catalytic converter is reached fairly quickly. To ensure. This also ensures that the catalytic converter is arranged in close proximity to the engine. It is particularly advantageous here that the catalytic converter is connected directly to the internal combustion engine, in particular arranged in the exhaust manifold. Each of the plurality of small converters can be fixed in a separate exhaust section of the exhaust manifold, in which case the plurality of small converters are preferably fixed directly at the connection point of the internal combustion engine and the exhaust manifold. The thermal light-off performance of the catalytic converter is significantly improved by the proximity of the cylinder or combustion chamber of the internal combustion engine.
    [14] According to another configuration of the exhaust system, the oxidation catalytic converter has two or more zones, wherein the zone furthest from the internal combustion engine is configured to have a higher specific heat capacific than the other zones. . Oxidation catalytic converters typically have a honeycomb structure in which partitions form passages through which exhaust gases can flow. For example, by making the partitions thicker, it is possible to ensure an increase in specific heat (particularly surface area-specific heat). For example, if the partitions in the upstream zone of the oxidation catalytic converter have a thickness of less than 0.03 mm, the partitions of the central zone have a thickness of approximately 0.03 mm to 0.06 mm, while the partitions of the downstream zone have a thickness of at least 0.08 mm. The number of zones and the thickness of the bulkhead are particularly oriented to the exhaust gases of a particular composition and their thermal energy. The increase in specific heat in the flow direction means that the oxidation catalytic converter of the upstream zone reaches its operating temperature at the earliest stage, and the catalytic reaction resulting therefrom also delivers sufficient exothermic energy for the downstream zone to be heated rapidly. do. In this case, the zone with the highest heat capacity takes the form of a heat reservoir even after the internal combustion engine is shut down, for example, significantly reducing the cold-start state after restart.
    [15] According to another configuration of the exhaust system, the particle trap is arranged immediately downstream of the oxidation catalytic converter, in the flow direction, preferably at a distance of less than 50 mm, in particular at a distance of less than 20 mm. If the exhaust system is configured in this way, it is particularly advantageous to accommodate particle traps and oxidation catalytic converters in a common housing. In the present specification, preferred in the examples is that the oxidation catalytic converter is integrated into the particle trap, which particle trap preferably has a catalytically active coating. This enables particularly space-saving arrangements of oxidation catalytic converters and particle traps, which are particularly important in terms of arranging the exhaust system adjacent to the engine.
    [16] According to another configuration of the exhaust system, the particle trap has a total volume of less than 75%, in particular less than 50%, preferably less than 25% of the volume of the internal combustion engine. Under some circumstances, such as when arranged adjacent to the engine and / or during the regeneration of a fairly short discrete particle trap, the total volume is further increased to a size less than 5% or less than 1% of the volume of the internal combustion engine, if appropriate. It is also possible to reduce. As used herein, the term, volume, should be understood to mean the sum of the volumes of the combustion chambers or cylinders of the internal combustion engine where combustion of fuel occurs.
    [17] Thus, particle traps have a fairly small total volume, which on the one hand ensures a space-saving arrangement and, on the other hand, an effective chemical conversion of the particles. Particle traps can be particularly compact due to the fact that upstream catalytic converters produce nitrogen dioxide that ensures continuous regeneration of particle traps and does not require large storage volumes for the carbon-based particles to be converted. have.
    [18] In this specification, it is advantageous for the particle trap to have a freely accessible passageway, which is arranged with turbulence points and calming points and / or diverter devices. This increases the likelihood that particles (particularly carbon-based particles) in the particle trap will react with the oxides of nitrogen in a simple manner by extending the residence time. This is achieved by having a sufficient number of turbulent and quiet points and / or diverter devices in the case of flow paths that are inherently freely accessible to facilitate the deposition of particles on the wall. Particles flying along the exhaust gas stream have a small chance of reacting with other components of the exhaust gas, but if the particles stop at turbulent or calm points or are deposited on the septum, this opportunity is greatly increased. Thereafter, all of the nitrogen dioxide moving forward is available for the reaction so that the particles are quickly destroyed. As a result, the particle trap is not interrupted and is continuously regenerated.
    [19] According to another configuration of the exhaust system, the catalytic converter has a converter volume of less than half the catalytic converter volume of the oxidation catalytic converter. The terms converter volume and catalytic converter volume mean in each case the external volume (wall + passage) of one or more converters or oxidation catalytic converters. The compact construction of this catalytic converter aids light-off performance and promotes space-saving arrangements.
    [20] According to another configuration of the exhaust system, at least one, and preferably each part of the exhaust system has a honeycomb with a passage through which the exhaust gas can flow, the honeycomb being at least partially structured. It is formed of a metal foil. In this case, this honeycomb of the converter and / or the oxidation catalyst converter has a passage density of at least 600 cpsi (number of cells per in 2 ), in particular 1000 cpsi. The cross sectional area of the particle trap is required to be slightly larger than the passage cross sectional area, which means that the particle trap should be configured with a passage density of at least 200 cpsi, in particular 400 cpsi or 600 cpsi, in which case sufficient area to accommodate the particles is always available. Do. If the oxidation catalytic converter consists of a honeycomb comprising a metal foil of this property, the metal foil preferably has a thickness of less than 0.06 mm, in particular less than 0.03 mm.
    [21] The exhaust system according to the invention is described in more detail on the basis of particularly preferred embodiments shown in the drawings.
    [42] 1 is a schematic perspective view of an exhaust system 1 for purifying exhaust gas coming from a diesel engine. In this exhaust system, the exhaust gas starting from the internal combustion engine 2 flows through the exhaust system 1 in the preferred flow direction 3. This exhaust system 1 is particularly contained in a catalytic converter 4 for converting carbon monoxide and hydrocarbons contained in the exhaust gas, in particular an oxidation catalytic converter 5 for converting nitrogen monoxide contained in the exhaust gas, and in the exhaust gas. And a particle trap 6 for trapping the particles, in particular carbon-based particles, continuously in the flow direction 3. In some cases the illustrated exhaust system 1 has a plurality of exhaust sections downstream of the turbocharger 7, wherein the embodiment shown here comprises two catalytic converters arranged in close proximity to the internal combustion engine 2. 4) is installed. In this case, it is also possible to arrange the catalytic converter 4 in the exhaust section of one or more exhaust manifolds 8, which are connected directly to the internal combustion engine 2. The illustrated oxidation catalytic converter 5 has a plurality of zones 9, which have an increasing specific heat as shown in the flow direction 3 of the exhaust gas. The particle trap 6 is arranged just downstream of the oxidation catalytic converter 5 at a distance of less than 50 mm as shown in the flow direction 3. The particle trap 6 here has a total volume 11 which is preferably less than 75% of the volumetric capacity 12 of the internal combustion engine 2. This volume 12 corresponds to the sum of the individual volumes of the cylinders 21 of the internal combustion engine 2. The catalytic converter 4 is also configured as a converter volume 17 which is less than half the catalytic converter volume 18 of the oxidation catalytic converter 5. In this case, it is to be understood that the final converter volume 17 means the sum of the volumes of the catalytic converter 4.
    [43] The exhaust system 1 shown is preferably arranged in close proximity to the internal combustion engine 2. In this specification, it is important to avoid having one of the parts 4, 5, 6 arranged in the underbody of the motor vehicle.
    [44] 2 is a plan view of an oxidation catalytic converter 5 or catalytic converter 4 with a honeycomb 19. This honeycomb 19 is formed by at least partially structured metal foil 20 and has a passage 13 through which exhaust gas can flow. To this end, the flat metal foil 23 and the structured metal foil 20 are initially stacked and then wound and a honeycomb 19 is arranged in the tubular casing 22 to increase the stability of the part. The honeycomb 19 is preferably configured to have a catalyst coating, which is characterized by a particularly high fissured surface and thus a high level of efficiency for the conversion of contaminants. Have
    [45] 3 is a schematic, perspective, detailed view of the particle trap 6. This particle trap 6 consists of a flat metal foil 23 with a hole 24 and a structured metal foil 20, forming a freely accessible passage 13. Wing-shaped diverter devices 16 with openings 25 achieve the effects described above. This diverter device 16 has a quiet point 15 and a turbulent point 14 which swirls the exhaust gas so that the particles remain in the particle trap 6 for a longer time. Thus, it becomes easier to react with other components of the exhaust gas. According to the precise configuration of this diverter device 16, the particles are also thrown on the metal foil 20, which particles continue to stick here. There, the carbon-based particles are chemically converted by nitrogen dioxide flowing through them continuously and efficiently so that free flow through the passage is always ensured.
    [46] 4 schematically shows another configuration of the exhaust system 1 arranged in proximity to the engine 2. This exhaust system 1 is used to purify the exhaust gas coming from the internal combustion engine 2, in particular from the diesel engine of a motor vehicle, which exhaust gas flows through the exhaust system 1 in the flow direction 3. This exhaust system 1 comprises in particular at least one catalytic converter 4 for converting carbon monoxide and hydrocarbons contained in the exhaust gas, in particular an oxidation catalytic converter 5 for changing nitrogen monoxide contained in the exhaust gas, and an exhaust gas. A particle trap 6 for collecting the particles contained therein is continuously included in the flow direction 3. In the illustrated embodiment, the catalytic converter 4 is arranged in particular proximity to the combustion chamber of the engine, specifically a small catalytic converter 4 is arranged in each outlet from the combustion chamber in the exhaust manifold 28. have. Thus, the catalytic converter 4 is also connected upstream of the turbocharger 7, which in particular is configured as an exhaust gas turbocharger, which is used to compress the fresh air supplied to the engine (fresh air). Supply 27).
    [47] In the case of the exhaust system 1 shown, the oxidation catalytic converter 5 and the particle trap 6 are arranged in a common housing 26, and the oxidation catalytic converter 5 is integrated in the particle trap 6. To this end, the particle trap 6 has a catalytically active coating in the same way as the oxidation catalytic converter 5. The particle trap 6 has a total volume 11 which is less than 75%, in particular less than 50%, preferably less than 25% of the volume 12 of the internal combustion engine 3. Particle traps 6 are arranged at a distance 29 from the engine to ensure that the highest possible temperature is present for regeneration of the particle trap 6 during operation of the internal combustion engine 2 and operation of the exhaust system 1. This distance is preferably 80 cm. In this specification, this distance 29 is preferably understood as meaning the path length covered by the exhaust gas before the exhaust gas reaches the particle trap 6.
    [48] The exhaust system according to the invention ensures a fairly effective conversion of contaminants (especially carbon monoxide, unsaturated hydrocarbons, nitrogen oxides, carbon-based particles) contained in exhaust gases from diesel engines, and in particular also relates to the regeneration of particle traps. Has a particularly positive effect. More precisely, due to the upstream catalytic converter, the production of increased nitrogen dioxide by the oxidation catalytic converter means that a sufficient amount of nitrogen dioxide is available in the particle trap to ensure continuous regeneration. This prevents passages from blocking and the emissions are well below the current exhaust emissions limits.
    权利要求:
    Claims (11)
    [1" claim-type="Currently amended] As an exhaust system 1 for purifying exhaust gases originating from the internal combustion engine 2 of a motor vehicle, in particular a diesel engine, which can flow in the flow direction 3,
    In particular a catalytic converter 4 for converting hydrocarbons and carbon monoxide contained in said exhaust gas,
    In particular an oxidation catalytic converter 5 for converting nitrogen monoxide contained in said exhaust gas, and
    An exhaust system continuously comprising along the flow direction (3) a particle trap (6) for collecting particles contained in said exhaust gas.
    [2" claim-type="Currently amended] 2. The exhaust system (1) according to claim 1, wherein the exhaust system (1) comprises a turbocharger (7),
    Viewed in the flow direction 3, the catalytic converter 4 is arranged upstream of the turbocharger 7 and the oxidation catalytic converter 5 shows that the turbocharger 7 is arranged downstream. Characterized by an exhaust system.
    [3" claim-type="Currently amended] 3. The catalytic converter (4) according to claim 1 or 2, wherein the catalytic converter (4) is arranged in close proximity to the internal combustion engine (2), in particular an exhaust manifold (8), and the exhaust manifold (8) is connected to the internal combustion engine (2). Exhaust system characterized in that it is directly connected.
    [4" claim-type="Currently amended] 4. The oxidation catalytic converter (5) according to any one of the preceding claims, wherein the oxidation catalytic converter (5) has at least two zones (9), wherein the zone (9) furthest from the internal combustion engine (2) An exhaust system, characterized in that it is configured to have a higher specific heat than the remaining zones of the at least one zone (9).
    [5" claim-type="Currently amended] 5. The particle trap 6 according to claim 1, directly in the flow direction 3, downstream of the oxidation catalytic converter 5, preferably less than 50 mm. 6. Exhaust system, in particular arranged at a distance (10) of less than 20 mm.
    [6" claim-type="Currently amended] 6. Exhaust system according to claim 5, characterized in that the oxidation catalytic converter (5) and the particle trap (6) are arranged in a common housing (26).
    [7" claim-type="Currently amended] 7. Exhaust system according to claim 6, characterized in that the oxidation catalytic converter (5) is integrated in the particle trap (6) and the particle trap (6) preferably has a catalytically active coating.
    [8" claim-type="Currently amended] The particle trap (6) according to any one of the preceding claims, wherein the particle trap (6) has a total volume (less than 75%, in particular less than 50%, preferably less than 25%) of the volume of the internal combustion engine (2). 11) exhaust system characterized in that it has.
    [9" claim-type="Currently amended] 9. The freely accessible passageway according to any one of the preceding claims, wherein the particle trap (6) is arranged with a turbulent point (14) and a quiet point (15) and / or a diverter device (16) arranged therein. (13), an exhaust system characterized by the above-mentioned.
    [10" claim-type="Currently amended] 10. The exhaust gas according to any of the preceding claims, characterized in that the catalytic converter (4) has a converter volume (17) which is less than half the catalytic converter volume (18) of the oxidation catalytic converter (5). system.
    [11" claim-type="Currently amended] The passage according to any one of the preceding claims, wherein at least one of the exhaust systems (1), and preferably each of the components (4, 5, 6), is capable of flowing through the exhaust gas. An exhaust system, characterized in that it has a honeycomb (19) for (13), which honeycomb is formed of at least partially structured metal foil (20).
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    同族专利:
    公开号 | 公开日
    CN1272089C|2006-08-30|
    EP1379322B1|2005-07-13|
    ES2245969T5|2012-06-27|
    US20040074231A1|2004-04-22|
    EP1379322A1|2004-01-14|
    JP2004525296A|2004-08-19|
    EP1379322B2|2012-04-04|
    US8166750B2|2012-05-01|
    ES2245969T3|2006-02-01|
    WO2002083274A1|2002-10-24|
    DE10118327A1|2002-10-17|
    US20050005597A1|2005-01-13|
    CN1602224A|2005-03-30|
    KR100814204B1|2008-03-17|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    法律状态:
    2001-04-12|Priority to DE10118327.5
    2001-04-12|Priority to DE10118327A
    2001-10-11|Application filed by 에미텍 게젤샤프트 퓌어 에미시온스테크놀로기 엠베하
    2001-10-11|Priority to PCT/EP2001/011744
    2004-01-31|Publication of KR20040010621A
    2006-04-12|First worldwide family litigation filed
    2008-03-17|Publication of KR100814204B1
    2008-03-17|Application granted
    优先权:
    申请号 | 申请日 | 专利标题
    DE10118327.5|2001-04-12|
    DE10118327A|DE10118327A1|2001-04-12|2001-04-12|Diesel exhaust purification system for automobiles, comprises oxidative catalysts converting carbon monoxide, hydrocarbon and nitrogen oxides, followed by particle trap|
    PCT/EP2001/011744|WO2002083274A1|2001-04-12|2001-10-11|Exhaust gas system|
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